碳纤维镀镍

碳纤维是一种新型的高强度、高模量材料,具有良好的导电能力.以镀镍碳纤维增强的复合材料具有高的比强度、比模量、比刚度和良好的高温性能及尺寸稳定性.本文介绍了碳纤维表面化学镀镍及电镀镍的原理和工艺流程,其中镀前预处理对整个施镀过程至关重要.化学镀镍除Ni-P体系外还有Ni-B体系.     

降低不溶阳极电积镍直流电耗的探讨

对影响不溶阳极电积镍直流电耗的各种因素进行了分析,降低溶液电阻、减少线路损耗可降低槽电压,而稳定阴极液pH、适当提高溶液中镍离子和H3BO3浓度对提高电流效率、降低直流电耗有利,采取相应措施后,取得了良好效果,直流电耗降低了5%,经济效益明显。     

表面包覆法制备高固相含量SiC悬浮液的研究

本工作试图通过有机包覆的方法改善SiC粉在水中的表面胶体特性，制备高固相体积分数的SiC粉体悬浮液。以制备的悬浮液的固相体积分数为衡量标准，分别确定了APS和PAAM包覆过程最佳条件．（1）APS包覆：时间为5h，温度90℃，APS的质量分数为5％，此条件下可以制得固相体积分数为45％的SiC悬浮液；（2）PAAM包覆：时间为5h，温度30℃，AAM的质量分数为2％，在此条件下可以制得固相体积分数为50％的SiC悬浮液．     

镁合金微弧氧化研究

在两种体系中研究了镁合金的微弧氧化.对比实验表明,磷酸盐体系中钕对氧化膜外观、厚度和耐蚀性有较大改善,提高钕盐浓度效果更佳;硅酸盐体系中,用稀土盐溶液浸泡试样后,制得的试样表面颜色较白,膜层分布更均匀,起弧容易.两种体系中用稀土转化膜取代镁合金表面的自然氧化膜进行微弧氧化处理,获得的陶瓷层分布更加均匀,表面更光滑致密,耐蚀性显著加强.     

300 kA大型电解槽阴极新材料的应用

对我国伊川电解铝厂300 kA大型预焙槽进行大修时,采用了不同石墨质的碳阴极、振动成型TiB2涂层阴极和刷涂TiB2涂层阴极等新材料,通过研究电解槽启动后一段时间内不同阴极材料的炉底电压降、电阻随时间的变化关系和铝液中Ti含量的变化规律等,寻找综合性能较佳的阴极材料,使其可达到降低炉底压降,形成完好的炉帮,从而有效地提高槽寿命的目的.研究发现TiB2质量分数为30%的振动成型阴极碳块的阴极电压降和铝中Ti的质量分数均较低,分别为261mV和0.002 5%;认为采用全石墨化阴极和振动成型硼化钛涂层阴极可以节省电能降耗.     

气体辅助法陶瓷薄膜的制备

Ceramics （alumina） coating on sevaral materials has been successfully achieved at room temperature by gas - assisted deposition （ GAD） technique. In the GAD process the alumina powder was accelerated by jet flow with velocity of - 1000 m/s and impaeted to a substrate, thereby a fiat and dense film was deposited up to 10 μm on the substrate without arty additional heating. The crystal structttre of the alumina in an obtained GAD films seemed as amorphous like. The crystalline phase was recovered by post nnnenling at 1 300 ℃ , however, the matrix resulted in a hollow structure.     

超细镍粉的化学还原制备及其分散剂的作用

采用溶液还原法，以硫酸镍为原料，水合肼为还原剂制备了超细和纳米镍粉。研究了不同分散剂对镍粉粒度和粒度分布的影响。X射线衍射结果表明，所得粉末为纯Ni相，晶粒尺寸约13nm；激光粒度分布测试结果表明，Ni粉粒度分布较窄，中位径集中在0．7～0．8μm，最大粒径不超过2．0μm。透射电镜照片显示粉末近球形，一次颗粒粒径在50～100nm之间，有轻微团聚。改变分散剂种类（PVP、PEG1500、PEG20000、CTAC）和用量可使超细镍粉的比表面积在3．24～57．88m^2／g间变化。     

Influence of Interfacial Diffusion on Mechanical Property of Vacuum Fusion Sinter （VFS） WC-Co Composite Coating

The WC-Co composite coatings bonded tightly to steel substrate have been made by vacuum fusion sinter （VFS）. The concentration distribution of some components were measured by the electron probe, and the microstructure and morphology of VFS coatings were observed and analyzed by SEM, X-ray diffractometer and microhardness tester. Diffusion coefficient of every element was calculated by using the experimental results. The influence of the interracial diffusion on the microstructure, Vickers hardness and interracial bond strength of the VFS coatings was studied in detail. The experimental results show that there is a metallurgical bond area between the VFS WC-Co coatings and the steel substrate. The VFS coatings are characterized by the gradient hardness of the interface and the high bond strength to the steel substate, both of which are beneficial to the improvement of the wear resistance and corrosion resistance.     

Microstructure of Fe-Based Alloy Hardfacing Coating Reinforced by TiC-VC Particles

Mierostrueture of the Fe-based alloy hardfaeing coating reinforced by TiC-VC particles was investigated by means of SEM, TEM, XRD and EPMA. The thermodynamics and effect of elements on the carbides were discussed. The result shows that TiC-VC carbides can be formed during arc welding. Carbides with particle size of 2 ～4μm are uniformly dispersed in the matrix. Evidently the covering components and their amount affect the microstrueture and hardness of the coatings. An excellent microstructure and hardness of hardfacing coating were obtained, while the amount of graphite, FeTi and FeV was controlled within the range of 8%- 10%, 15%- 18% and 8%- 12%, respectively.     

热镀锌板温度测量数据辨识模型探索与应用

介绍了热镀锌机组带钢进入锌锅的温度控制原理,针对板温控制建立了温度测量数据辨识模型,即用等温辐射针对温度进行测量的辨识模型,介绍了基于辨识模型的生产实践和取得的效果。